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Kevin de Bruyne has 111 caps for Belgium Belgian midfielder Kevin de Bruyne scored on his Napoli debut as the Serie A champions began their title defence with a 2-0 win at Sassuolo. The 34-year-old, who joined on a free transfer in the summer after 10 years with Manchester City, found the far corner of the net with a whipped free-kick from the left shortly before the hour mark. Scotland midfielder Scott Mc Tominay had given the champions the lead after 17 minutes when he headed in a cross from Italy winger Matteo Politano. Mc Tominay, 28, scored 12 goals in 34 league appearances after joining Napoli from Manchester United in 2024, earning him the Serie A MVP award as Antonio Conte's side clinched the title. The Scot, who has scored 14 times in 37 matches in all competitions for the Italians, recently earned a nomination for the 2025 Ballon d'Or award. The hosts' on-loan Marseille midfielder Ismael Kone was sent off with 11 minutes to go for a second bookable offence. Elsewhere in the division, Genoa and Lecce played out a tense 0-0 draw in a game of few chances. 'In our DNA' - how the Scots took over Italian football Last Updated 23rd August 2025 at 20: 59 Please Note: All times UK. Tables are subject to change. The BBC is not responsible for any changes that may be made. Manager: Fabio Grosso Formation: 4 - 3 - 3 Manager: Antonio Conte Formation: 4 - 1 - 4 - 1 Manager: Fabio Grosso Formation: 4 - 3 - 3 Manager: Antonio Conte Formation: 4 - 1 - 4 - 1 Serie A All competitions All competitions All competitions Match ends, Sassuolo 0, Napoli 2. Second Half ends, Sassuolo 0, Napoli 2. Foul by David Neres (Napoli). Alieu Fadera (Sassuolo) wins a free kick in the defensive half. Attempt missed. Daniel Boloca (Sassuolo) right footed shot from the centre of the box is high and wide to the right. Assisted by Nicholas Pierini. Attempt missed. Frank Anguissa (Napoli) right footed shot from the centre of the box is high and wide to the right. Assisted by Leonardo Spinazzola. Fourth official has announced 5 minutes of added time. Substitution, Sassuolo. Nicholas Pierini replaces Domenico Berardi. Substitution, Sassuolo. Luca Moro replaces Andrea Pinamonti. Substitution, Napoli. Antonio Vergara replaces Scott Mc Tominay. Substitution, Napoli. Leonardo Spinazzola replaces Mathías Olivera. Delay over. They are ready to continue. Delay in match because of an injury David Neres (Napoli). Delay in match because of an injury Fali Candé (Sassuolo). Attempt missed. Andrea Pinamonti (Sassuolo) right footed shot from outside the box is high and wide to the right. Assisted by Fali Candé with a headed pass. Frank Anguissa (Napoli) wins a free kick in the attacking half. Foul by Tarik Muharemovic (Sassuolo). Alex Meret (Napoli) wins a free kick in the defensive half. Foul by Tarik Muharemovic (Sassuolo). Corner, Sassuolo. Conceded by Amir Rrahmani. Copyright © 2025 BBC. The BBC is not responsible for the content of external sites. Read about our approach to external linking.